趙凱，博士，副教授
電子郵箱：[email protected]
研究方向：
1. 新能源材料
2. 固體氧化物燃料電池
3. 燃料重整催化劑
科研項(xiàng)目
1. 國(guó)家自然科學(xué)基金青年科學(xué)基金項(xiàng)目,，項(xiàng)目名稱：催化層支撐型固體氧化物燃料電池陽(yáng)極催化劑設(shè)計(jì)與催化性能研究,，22005051。
2. 廣東省基礎(chǔ)與應(yīng)用基礎(chǔ)研究基金項(xiàng)目–廣東省自然科學(xué)基金–面上項(xiàng)目,，項(xiàng)目名稱：催化層支撐型固體氧化物電解池CuFe基陰極催化劑構(gòu)筑與催化性能研究，2022A1515012001。
3. 廣東省普通高?？蒲许?xiàng)目–青年創(chuàng)新人才類項(xiàng)目，項(xiàng)目名稱：固體氧化物燃料電池陽(yáng)極催化劑在電場(chǎng)下的協(xié)同催化機(jī)理研究,，2019KQNCX166,。
4. 廣東省基礎(chǔ)與應(yīng)用基礎(chǔ)研究基金項(xiàng)目–區(qū)域聯(lián)合基金–青年基金項(xiàng)目，項(xiàng)目名稱：固體氧化物燃料電池陽(yáng)極催化劑構(gòu)筑及催化機(jī)理研究,，2019A1515110237,。
論文成果
[1] K. Zhao, J. Lu, L. Le, C. Coyle, O.A. Marina, K. Huang, A high-performance intermediate temperature reversible solid oxide cell with a new barrier layer free oxygen electrode, Applied Energy, 361 (2024) 122962.
[2] J. Luo, K. Zhao*, J. Zhao, J. Li, Y. Liu, D. Chen, Q. Xu, M. Chen, Functional ceramic support as an independent catalyst layer for direct liquid fuel solid oxide fuel cells, Journal of Advanced Ceramics, 12 (2023) 474-486.
[3] J. Li, Y. Zhang, K. Zhao, S.P. Jiang, M. Chen, An investigation of Cr vaporization from SUS430 metallic interconnect and deposition on (La,Sr)MnO3 cathode of intermediate temperature solid oxide fuel cells, Journal of Power Sources, 579 (2023) 233285.
[4] J. Wang, K. Zhao*, J. Zhao, J. Li, Y. Liu, D. Chen, Q. Xu, M. Chen, A NiMo-YSZ catalyst support layer for regenerable solid oxide fuel cells running on isooctane, Applied Energy, 326 (2022) 119907.
[5] M. Chen, K. Zhao, J. Zhao, X. Wang, J. Li, Q. Xu, Accelerated kinetics of hydrogen oxidation reaction on the Ni anode coupled with BaZr0.9Y0.1O3-δ proton-conducting ceramic electrolyte via tuning the electrolyte surface chemistry, Applied Surface Science, 605 (2022) 154800.
[6] Z. Lin, K. Zhao*, G. Cheng, S. Hu, M. Chen, J. Li, D. Chen, Q. Xu, M. Chang, O. Volodymyr, Catalyst layer supported solid oxide fuel cells running on methane, Journal of Power Sources, 507 (2021) 230317.
[7] K. Zhao, G. Cheng, S. Hu, S. Ha, M.G. Norton, M. Chen, D. Chen, Q. Xu, B.-H. Kim, NiMo-calcium-doped ceria catalysts for inert-substrate-supported tubular solid oxide fuel cells running on isooctane, International Journal of Hydrogen Energy, 45 (2020) 29367-29378.
[8] Q. Bkour, F. Che, K.M. Lee, C. Zhou, N. Akter, J.A. Boscoboinik, K. Zhao, J. Gray, S.R. Saunders, M. Grant Norton, J.-S. McEwen, T. Kim, S. Ha, Enhancing the partial oxidation of gasoline with Mo-doped Ni catalysts for SOFC applications: An integrated experimental and DFT study, Applied Catalysis B: Environmental, 266 (2020) 118626.
[9] K. Zhao, X. Hou, M.G. Norton, S. Ha, Application of a NiMo–Ce0.5Zr0.5O2-δ catalyst for solid oxide fuel cells running on gasoline, Journal of Power Sources, 435 (2019) 226732.
[10] K. Zhao, Q. Bkour, B.H. Kim, M.G. Norton, S. Ha, NiMo-Ceria-Zirconia Catalyst for Inert-Substrate-Supported Tubular Solid Oxide Fuel Cells Running on Model Gasoline, Energy Technology, 7 (2019) 48-52.
[11] X. Hou, K. Zhao, O.A. Marina, M. Grant Norton, S. Ha, NiMo-ceria-zirconia-based anode for solid oxide fuel cells operating on gasoline surrogate, Applied Catalysis B: Environmental, 242 (2019) 31-39.
[12] K. Zhao, B.H. Kim, M.G. Norton, S.Y. Ha, Cathode Optimization for an Inert-Substrate- Supported Tubular Solid Oxide Fuel Cell, Frontiers in Energy Research, 6 (2018) 87.
[13] K. Zhao, X. Hou, Q. Bkour, M.G. Norton, S. Ha, NiMo-ceria-zirconia catalytic reforming layer for solid oxide fuel cells running on a gasoline surrogate, Applied Catalysis B: Environmental, 224 (2018) 500-507.
[14] K. Zhao, Q. Bkour, X. Hou, S.W. Kang, J.C. Park, M.G. Norton, J.-I. Yang, S. Ha, Reverse water gas shift reaction over CuFe/Al2O3 catalyst in solid oxide electrolysis cell, Chemical Engineering Journal, 336 (2018) 20-27.
[15] S. Han, Y.Q. Lei, Q. Xu, D.P. Huang, M. Chen, K. Zhao, D.C. Chen, F. Zhang, Beneficial effect of oxygen-ion conductor infiltration on the electrocatalytic properties of a heavily strontium-doped lanthanum nickelate Ruddlesden-Popper SOFC cathode, Ionics, 30 (2024) 2177-2189.
[16] Z.X. Zhang, X.B. Xie, Q. Xu, D.-P. Huang, M. Chen, K. Zhao, D.C. Chen, F. Zhang, Alleviated surface calcium segregation and improved electrocatalytic properties of La0.3Ca0.7Fe0.7Cr0.3O3-δ cathode: A demonstration of A-site deficiency effect, Journal of Alloys and Compounds, 924 (2022) 166615.
[17] L. Wang, X.B. Xie, Q. Xu, D.P. Huang, M. Chen, K. Zhao, D.C. Chen, F. Zhang, Improved electrocatalytic properties of strontium-doped lanthanum nickelate cathodes by infiltrating samarium-doped ceria, Ionics, 28 (2022) 1873-1885.
[18] X.B. Xie, Q. Xu, D.P. Huang, J. Xiao, M. Chen, K. Zhao, D.C. Chen, F. Zhang, An insight into the electrocatalytic properties of porous La0.3Sr0.7Fe0.7Cr0.3O3-δ electrodes towards oxygen reduction reaction, Journal of Solid State Electrochemistry, 25 (2021) 1007-1018.
[19] X.B. Xie, Q. Xu, D.P. Huang, J. Xiao, M. Chen, K. Zhao, D.C. Chen, F. Zhang, Insights into surface alkaline-earth segregation on the surface of La0.3Me0.7Fe0.7Cr0.3O3-δ (Me = Sr, Ca) porous electrodes for oxygen reduction reaction, Applied Surface Science, 566 (2021) 150659.
[20] Y.P. Wang, K. Zhao, Q. Xu, D.P. Huang, M. Chen, B.H. Kim, Optimization on the electrochemical properties of La2NiO4+δ cathodes by tuning the cathode thickness, International Journal of Hydrogen Energy, 43 (2018) 4482-4491.
[21] K. Zhao, Y. Du, Calcium-doped ceria materials for anode of solid oxide fuel cells running on methane fuel, Journal of Power Sources, 347 (2017) 79-85.
[22] B. Han, K. Zhao, X. Hou, D.J. Kim, B.H. Kim, S. Ha, M.G. Norton, Q. Xu, B.G. Ahn, Ni-(Ce0.8-xTix)Sm0.2O2-δ anode for low temperature solid oxide fuel cells running on dry methane fuel, Journal of Power Sources, 338 (2017) 1-8.
[23] Q. Bkour, K. Zhao, L. Scudiero, D.J. Han, C.W. Yoon, O.G. Marin-Flores, M.G. Norton, S. Ha, Synthesis and performance of ceria-zirconia supported Ni-Mo nanoparticles for partial oxidation of isooctane, Applied Catalysis B: Environmental, 212 (2017) 97-105.
[24] K. Zhao, B.H. Kim, Y. Du, Q. Xu, B.G. Ahn, Ceria catalyst for inert-substrate-supported tubular solid oxide fuel cells running on methane fuel, Journal of Power Sources, 314 (2016) 10-17.
[25] Y.P. Wang, Q. Xu, D.P. Huang, K. Zhao, M. Chen, B.H. Kim, Evaluation of La1.8Sr0.2NiO4+δ as cathode for intermediate temperature solid oxide fuel cells, International Journal of Hydrogen Energy, 41 (2016) 6476-6485.
[26] X. Hou, K. Zhao, J.I. Yang, S. Ha, MoO2-based cathode for CO2 and H2O electrolysis, International Journal of Hydrogen Energy, 41 (2016) 11895-11899.
[27] K. Zhao, B.H. Kim, Q. Xu, Y. Du, B.G. Ahn, Redox cycling performance of inert-substrate-supported tubular single cells with nickel anode current collector, Journal of Power Sources, 293 (2015) 336-342.
[28] K. Zhao, B.H. Kim, Q. Xu, B.-G. Ahn, Performance improvement of inert-substrate-supported tubular single cells via microstructure modification, Journal of Power Sources, 274 (2015) 799-805.
[29] L. Ma, K. Zhao, B.H. Kim, Q. Li, J. Huang, Electrochemical performance of solid oxide fuel cells with Sm, Nd co-doped Ce0.85(SmxNd1-x)0.15O2-δ electrolyte, Ceramics International, 41 (2015) 6391-6397.
[30] K. Zhao, Y.P. Wang, M. Chen, Q. Xu, B.H. Kim, D.P. Huang, Electrochemical evaluation of La2NiO4+δ as a cathode material for intermediate temperature solid oxide fuel cells, International Journal of Hydrogen Energy, 39 (2014) 7120-7130.
[31] K. Zhao, B.H. Kim, Q. Xu, B.G. Ahn, Fabrication and characterization of inert-substrate- supported tubular single cells by dip-coating process, Journal of Power Sources, 245 (2014) 671-677.
專利授權(quán)
[1] 趙凱, 陳旻, 陳東初, 徐慶, 一種SOFC的陽(yáng)極催化層支撐體和制備方法及其應(yīng)用, ZL 2020 1 0895094.9, 2020.08.31。
[2] 趙凱, 陳旻, 陳東初, 徐慶, 一種層狀結(jié)構(gòu)的Lan+1NinO3n+1固體氧化物燃料電池陽(yáng)極催化劑, ZL 2022 1 0626066.6, 2022.06.02,。
